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    Sodium chlorite is derived indirectly from sodium chlorate, NaClO 3. First, sodium chlorate is reduced to chlorine dioxide, typically in a strong acid solution using reducing agents such as sodium sulfite, sulfur dioxide, or hydrochloric acid.

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    Sodium chlorate is a strong oxidizer that has applications as an herbicide and in the mining industry. Sodium chlorate was traditionally the first choice oxidant in North American uranium plants. It is clear that each mole of sodium chlorate requires 3 moles of acid. In Southern Africa sodium chlorate was not considered as an oxidant due to .

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